Bonus
Complexes of this element’s trivalent ion and either di·pi·valo·metha·nato- or hepta·fluoro·octa·dio·nato- bidentate ligands can be used as chemical shift reagents for NMR. For 10 points each:
[10h] Name this element whose 3+ ion generates strong pseudocontact shifts from having six half-filled 4f orbitals. This element’s 2+ ion is the most common activating dopant for strontium aluminate phosphors.
ANSWER: europium [or Eu; accept europium(III) or Eu(III); accept europium(II) or Eu(II)]
[10e] The most common variants of NMR rely on either detecting protons or carbon atoms with this mass number, one higher than the most common carbon isotope.
ANSWER: 13 [or carbon-13]
[10m] Before using europium-based chemical shift reagents, NMR experiments are calibrated with respect to this molecule, whose single 12-proton peak has a chemical shift of zero.
ANSWER: tetramethylsilane [or TMS]
<Chemistry>
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Conversion
Team | Opponent | Part 1 | Part 2 | Part 3 | Total | Parts |
---|---|---|---|---|---|---|
British Columbia | Columbia A | 10 | 10 | 10 | 30 | HEM |
Chicago A | WUSTL B | 10 | 10 | 0 | 20 | HE |
Cornell A | LSE | 10 | 10 | 10 | 30 | HEM |
Florida | MIT | 0 | 10 | 0 | 10 | E |
Georgia Tech | Columbia B | 0 | 10 | 0 | 10 | E |
Harvard | Waterloo A | 0 | 0 | 10 | 10 | M |
Illinois A | Penn State | 10 | 10 | 10 | 30 | HEM |
Illinois B | Yale | 0 | 10 | 10 | 20 | EM |
Indiana | WUSTL A | 0 | 10 | 10 | 20 | EM |
Iowa State | Cornell B | 0 | 10 | 0 | 10 | E |
Johns Hopkins | UC Berkeley B | 0 | 10 | 10 | 20 | EM |
NYU | Rutgers | 0 | 0 | 10 | 10 | M |
North Carolina A | Maryland | 0 | 10 | 10 | 20 | EM |
Ohio State | Northwestern | 10 | 10 | 10 | 30 | HEM |
RIT | Chicago B | 0 | 10 | 0 | 10 | E |
Texas | Waterloo B | 0 | 10 | 10 | 20 | EM |
Toronto B | Minnesota | 0 | 10 | 10 | 20 | EM |
Toronto C | Virginia | 10 | 10 | 10 | 30 | HEM |
UC Berkeley A | Toronto A | 0 | 10 | 10 | 20 | EM |
Virginia Tech | Georgia State | 0 | 10 | 0 | 10 | E |
Summary
Tournament | Exact Match? | Heard | PPB | Easy % | Medium % | Hard % |
---|---|---|---|---|---|---|
2025 ACF Nationals | Yes | 20 | 19.00 | 90% | 70% | 30% |