Bonus

Complexes of this element’s trivalent ion and either di·pi·valo·metha·nato- or hepta·fluoro·octa·dio·nato- bidentate ligands can be used as chemical shift reagents for NMR. For 10 points each:
[10h] Name this element whose 3+ ion generates strong pseudocontact shifts from having six half-filled 4f orbitals. This element’s 2+ ion is the most common activating dopant for strontium aluminate phosphors.
ANSWER: europium [or Eu; accept europium(III) or Eu(III); accept europium(II) or Eu(II)]
[10e] The most common variants of NMR rely on either detecting protons or carbon atoms with this mass number, one higher than the most common carbon isotope.
ANSWER: 13 [or carbon-13]
[10m] Before using europium-based chemical shift reagents, NMR experiments are calibrated with respect to this molecule, whose single 12-proton peak has a chemical shift of zero.
ANSWER: tetramethylsilane [or TMS]
<Chemistry>
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Summary

TournamentExact Match?HeardPPBEasy %Medium %Hard %
2025 ACF NationalsYes2019.0090%70%30%