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Prior to calculating these constructions, the reducible representations must be decomposed to find the stretching modes that comprise the basis set. For 10 points each:
[10h] Name these constructions, which can also be calculated by applying symmetry operations to vectors representing bonds in the projection operator method. These constructions serve as symbolic fragments of the non-central atoms of molecules.
ANSWER: SALCs (“salks”) [or symmetry-adapted linear combinations; prompt on LCAOs or linear combinations of atomic orbitals; reject “atomic orbitals” or “orbitals”]
[10m] The symmetries of SALCs are labeled using lowercase Mulliken symbols on the left side of these tables. These tables are used to predict a molecule’s behavior based on its point group.
ANSWER: character tables
[10e] The combination of SALCs is used to create these structures, also denoted by Mulliken symbols, although an asterisk is used to indicate whether they are bonding or antibonding.
ANSWER: molecular orbitals [or MOs; prompt on orbitals; reject “atomic orbitals”]
<Chemistry>
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TournamentExact Match?HeardPPBEasy %Medium %Hard %
2025 ACF NationalsYes2112.3886%38%0%